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- W2071802010 abstract "Gold(I) alkoxides, Au(OR)L (L = PPh3, PCy3; R = CH(CF3)2, CH2CF3, Ph) smoothly abstract a hydrogen from transition metal hydrides (MH = CoH(CO)4, MoHCp(CO)3, WHCp(CO)3, MnH(CO)5, WHCp(CO)2(PPh3)) to give corresponding dinuclear complexes LAu-M with liberation of equimolar amount of ROH. Similar reactions of gold(III) alkoxides, cis-AuMe2-(OR)L also give dinuclear intermediates LMe2Au-M, from which preferential reductive elimination of ethane takes place when M is more electron withdrawing." @default.
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- W2071802010 date "1997-10-01" @default.
- W2071802010 modified "2023-10-13" @default.
- W2071802010 title "Hydrogen Abstraction from Transition Metal Hydrides by Gold Alkoxides Giving Gold-Containing Heterodinuclear Complexes" @default.
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- W2071802010 doi "https://doi.org/10.1246/cl.1997.981" @default.
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