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• W2071809252 abstract "Dissociative electron attachment (DEA) measurements to nitromethane, CH3NO2, in the gas phase have been revisited by making use of a high mass-resolution sector field instrument. Anion efficiency curves for 16 negatively charged fragments have been measured in the electron energy region from about 0 to 16 eV with an energy resolution of ∼1 eV. Eight new anions have been detected, CH2NO2−, CHNO2−, CH2NO−, H2NO−, CH3−, CH2−, CH− and H−. The five most dominant product anions are NO2−, O−, OH−, CN− and CNO−, all of them featuring two high-energy resonances at about 5 eV and 10 eV. Formation of CH2NO2− at low electron energies has been explained in terms of DEA to highly vibrationally excited molecules. The standard enthalpy of formation of CH2NO2− and H−, CH2− and NO− radicals have been estimated as ΔfHg°(CH2NO2−) = –1.71 eV, ΔfHg°(H−) = 2.09 eV, ΔfHg°(CH2−) = 3.5 eV and ΔfHg°(NO−) = –1.93 eV, respectively." @default.
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• W2071809252 date "2008-04-01" @default.
• W2071809252 modified "2023-09-25" @default.
• W2071809252 title "Dissociative electron attachment to nitromethane" @default.
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• W2071809252 doi "https://doi.org/10.1016/j.ijms.2007.11.004" @default.
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