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- W2071813397 abstract "α-Alkoxy- und α-Acetoxy-percarbonsäure-tert.-butylester wurden dargestellt und durch Spektren oder Elementaranalyse charakterisiert. Ihr thermischer Radikalzerfall wurde präparativ und kinetisch untersucht. α-Alkoxy-percarbonsäureester sind eine Klasse neuer Tieftemperatur-Initiatoren, deren hohe Zerfallsfreudigkeit durch einen polaren Substituenteneffekt gedeutet wird. Der Einfluß der α-Acetoxygruppe auf die Thermolysegeschwindigkeit von Perestern ist geringer. Der unterschiedliche Einfluß von Methylgruppen in α-substituierten Percarbonsäureestern auf die Zerfallsgeschwindigkeit wird diskutiert. Organic Peroxides, X. Preparation and Thermolysis of tert-Butyl α-Alkoxy- and α-Acetoxypercarboxylates Several tert-butyl α-alkoxy- and α-acetoxypercarboxylates were prepared and characterized by spectra or analyses. The kinetics and the products of their thermolysis reactions were investigated and are interpreted by a polar effect on the homolytic perester fragmentation. Because of the greater rate enhancing effect of the alkoxy substituents as compared to the acetoxy group, α-alkoxypercarboxylates are interesting low temperature initiators. – The differing influence of α-methyl substituents in several classes of substituted tert-butylpercarboxylates on their rate of decomposition is noted and discussed." @default.
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- W2071813397 date "1971-02-01" @default.
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- W2071813397 title "Organische Peroxide, X. Darstellung und Thermolyse von α‐Alkoxy‐ und α‐Acetoxy‐percarbonsäure‐tert.‐butylestern" @default.
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- W2071813397 doi "https://doi.org/10.1002/cber.19711040228" @default.
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