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• W2071827537 abstract "Various lanthanide complexes have been shown to promote phosphodiester hydrolysis. Distribution of the available coordination sites of the lanthanides between the ligand and the labile water molecules has proved to be critical in determining the activity and stability of the complex in water at neutral pH. Since the final goal is to conjugate such hydrolytically active molecules to DNA oligomers, the design must include a functionality that can be made reactive in standard conjugation protocols. To that end, we have synthesized a nitrophenyl-derivatized TCMC-La3+ complex, and it is as active as the unmodified TCMC-La3+ in the transesterification of an RNA model substrate." @default.
• W2071827537 created "2016-06-24" @default.
• W2071827537 creator A5067444038 @default.
• W2071827537 creator A5082576930 @default.
• W2071827537 date "1998-08-01" @default.
• W2071827537 modified "2023-09-23" @default.
• W2071827537 title "Synthesis and phosphodiester transesterification activity of the La3+-complex of a novel functionalized octadentate ligand" @default.
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• W2071827537 doi "https://doi.org/10.1016/s0040-4039(98)01166-6" @default.
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