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• W2071832238 endingPage "752" @default.
• W2071832238 startingPage "746" @default.
• W2071832238 abstract "Abstract Embedding endohdedral metallofullerenes (EMFs) into electron donor–acceptor systems is still a challenging task owing to their limited quantities and their still largely unexplored chemical properties. In this study, we have performed a 1,3‐dipolar cycloaddition reaction of a corrole‐based precursor with Sc 3 N@C 80 to regioselectively form a [5,6]‐adduct ( 1 ). The successful attachment of the corrole moiety was confirmed by mass spectrometry. In the electronic ground state, absorption spectra suggest sizeable electronic communications between the electron acceptor and the electron donor. Moreover, the addition pattern occurring at a [5,6]‐bond junction is firmly proven by NMR spectroscopy and electrochemical investigations performed with 1 . In the electronically excited state, which is probed in photophysical assays with 1 , a fast electron‐transfer yields the radical ion pair state consisting of the one‐electron‐reduced Sc 3 N@C 80 and of the one‐electron‐oxidized corrole upon its exclusive photoexcitation. As such, our results shed new light on the practical work utilizing EMFs as building blocks in photovoltaics." @default.
• W2071832238 created "2016-06-24" @default.
• W2071832238 creator A5020699341 @default.
• W2071832238 creator A5026991224 @default.
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• W2071832238 creator A5067786421 @default.
• W2071832238 creator A5069744831 @default.
• W2071832238 creator A5078853797 @default.
• W2071832238 date "2014-11-11" @default.
• W2071832238 modified "2023-10-18" @default.
• W2071832238 title "Synthesis and Photophysical Properties of a Sc₃N@C₈₀-Corrole Electron Donor-Acceptor Conjugate" @default.
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