FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071852040> ?p ?o ?g. }

• W2071852040 endingPage "198" @default.
• W2071852040 startingPage "190" @default.
• W2071852040 abstract "Copper(II) complexes with a series of bibracchial lariat ethers are described. Independently of the nature of the counterion present (nitrate or perchlorate), the lariat ether N,N′-bis(2-aminobenzyl)-1,10-diaza-15-crown-5 (L1) always forms mononuclear complexes, whereas the lariat ethers N,N′-bis(2-aminobenzyl)-4,13-diaza-18-crown-6 (L2) and N,N′-bis(2-salicylaldiminobenzyl)-4,13-diaza-18-crown-6 (L3) only give binuclear compounds. The X-ray crystal structure of [CuL1](ClO4)2 shows a seven-coordinated copper(II) ion in a distorted (axially compressed) pentagonal-bipyramidal geometry. The X-ray crystal structure of [Cu2(L3-2H)](ClO4)2 confirms the binuclear nature of the compound with both metal ions having identical coordination environments and each one placed out of the crown hole but efficiently encapsulated by the corresponding pendant arm; each copper(II) ion is five-coordinated with an intermediate geometry between trigonal-bipyramidal and square-pyramidal (τ=0.40). The EPR spectra in frozen solution samples are in accordance with a stable coordinate pattern for the metal centre of ligand L1, yielding a rhombic distorted complex with axial compression in solution, in agreement with the X-ray crystal structure of [CuL1](ClO4)2. For the binuclear complexes of L2 and L3, the Cu(II) centres in solution can be distorted from their tetragonally elongated structures via interaction with ethanol and/or the nitrate counterion, leading to more than one species." @default.
• W2071852040 created "2016-06-24" @default.
• W2071852040 creator A5033539854 @default.
• W2071852040 creator A5072832793 @default.
• W2071852040 creator A5072958886 @default.
• W2071852040 creator A5073252198 @default.
• W2071852040 creator A5073824046 @default.
• W2071852040 creator A5074890335 @default.
• W2071852040 creator A5088606268 @default.
• W2071852040 creator A5090491171 @default.
• W2071852040 date "2001-05-01" @default.
• W2071852040 modified "2023-10-17" @default.
• W2071852040 title "Copper complexes with bibracchial lariat ethers: from mono- to binuclear structures" @default.
• W2071852040 cites W1998722626 @default.
• W2071852040 cites W1999161001 @default.
• W2071852040 cites W2010024813 @default.
• W2071852040 cites W2048645097 @default.
• W2071852040 cites W2053121082 @default.
• W2071852040 cites W2061128141 @default.
• W2071852040 cites W2072209104 @default.
• W2071852040 cites W2098399088 @default.
• W2071852040 cites W2105249240 @default.
• W2071852040 cites W2153752024 @default.
• W2071852040 cites W2950977415 @default.
• W2071852040 cites W2951165804 @default.
• W2071852040 cites W3139376248 @default.
• W2071852040 cites W4253222054 @default.
• W2071852040 doi "https://doi.org/10.1016/s0020-1693(01)00425-x" @default.
• W2071852040 hasPublicationYear "2001" @default.
• W2071852040 type Work @default.
• W2071852040 sameAs 2071852040 @default.
• W2071852040 citedByCount "32" @default.
• W2071852040 countsByYear W20718520402012 @default.
• W2071852040 countsByYear W20718520402014 @default.
• W2071852040 countsByYear W20718520402018 @default.
• W2071852040 countsByYear W20718520402022 @default.
• W2071852040 crossrefType "journal-article" @default.
• W2071852040 hasAuthorship W2071852040A5033539854 @default.
• W2071852040 hasAuthorship W2071852040A5072832793 @default.
• W2071852040 hasAuthorship W2071852040A5072958886 @default.
• W2071852040 hasAuthorship W2071852040A5073252198 @default.
• W2071852040 hasAuthorship W2071852040A5073824046 @default.
• W2071852040 hasAuthorship W2071852040A5074890335 @default.
• W2071852040 hasAuthorship W2071852040A5088606268 @default.
• W2071852040 hasAuthorship W2071852040A5090491171 @default.
• W2071852040 hasBestOaLocation W20718520402 @default.
• W2071852040 hasConcept C111592845 @default.
• W2071852040 hasConcept C112887158 @default.
• W2071852040 hasConcept C115624301 @default.
• W2071852040 hasConcept C116569031 @default.
• W2071852040 hasConcept C145148216 @default.
• W2071852040 hasConcept C158842870 @default.
• W2071852040 hasConcept C170493617 @default.
• W2071852040 hasConcept C178790620 @default.
• W2071852040 hasConcept C185592680 @default.
• W2071852040 hasConcept C194196696 @default.
• W2071852040 hasConcept C2780709120 @default.
• W2071852040 hasConcept C32909587 @default.
• W2071852040 hasConcept C34814092 @default.
• W2071852040 hasConcept C544153396 @default.
• W2071852040 hasConcept C544778455 @default.
• W2071852040 hasConcept C55493867 @default.
• W2071852040 hasConcept C71240020 @default.
• W2071852040 hasConcept C8010536 @default.
• W2071852040 hasConcept C92840921 @default.
• W2071852040 hasConceptScore W2071852040C111592845 @default.
• W2071852040 hasConceptScore W2071852040C112887158 @default.
• W2071852040 hasConceptScore W2071852040C115624301 @default.
• W2071852040 hasConceptScore W2071852040C116569031 @default.
• W2071852040 hasConceptScore W2071852040C145148216 @default.
• W2071852040 hasConceptScore W2071852040C158842870 @default.
• W2071852040 hasConceptScore W2071852040C170493617 @default.
• W2071852040 hasConceptScore W2071852040C178790620 @default.
• W2071852040 hasConceptScore W2071852040C185592680 @default.
• W2071852040 hasConceptScore W2071852040C194196696 @default.
• W2071852040 hasConceptScore W2071852040C2780709120 @default.
• W2071852040 hasConceptScore W2071852040C32909587 @default.
• W2071852040 hasConceptScore W2071852040C34814092 @default.
• W2071852040 hasConceptScore W2071852040C544153396 @default.
• W2071852040 hasConceptScore W2071852040C544778455 @default.
• W2071852040 hasConceptScore W2071852040C55493867 @default.
• W2071852040 hasConceptScore W2071852040C71240020 @default.
• W2071852040 hasConceptScore W2071852040C8010536 @default.
• W2071852040 hasConceptScore W2071852040C92840921 @default.
• W2071852040 hasIssue "1-2" @default.
• W2071852040 hasLocation W20718520401 @default.
• W2071852040 hasLocation W20718520402 @default.
• W2071852040 hasOpenAccess W2071852040 @default.
• W2071852040 hasPrimaryLocation W20718520401 @default.
• W2071852040 hasRelatedWork W1978550472 @default.
• W2071852040 hasRelatedWork W2018375843 @default.
• W2071852040 hasRelatedWork W2024494343 @default.
• W2071852040 hasRelatedWork W2071852040 @default.
• W2071852040 hasRelatedWork W2074889057 @default.
• W2071852040 hasRelatedWork W2086784376 @default.
• W2071852040 hasRelatedWork W2087542416 @default.
• W2071852040 hasRelatedWork W2093630338 @default.
• W2071852040 hasRelatedWork W2391117267 @default.

• next