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- W2071887682 abstract "A systematic study has been carried out on the three isomeric cyclohexanedicarboxylates (CHDCs) formed by cadmium and manganese with the three isomeric dicarboxylic acids, in the presence or absence of amines. The CHDCs have been prepared under hydrothermal conditions and their structures established by X-ray crystallography. We have been able to isolate two-dimensional layered structures of 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates and chain structures of 1,3- and 1,4-cyclohexanedicarboxylates. The infinite metal–oxygen–metal linkages are observed only in the case of the 1,2-dicarboxylate. In all the three isomeric cyclohexanedicarboxylates, the e,e conformation is most favored, although the 1,4-CHDCs often contain rings in both the e,e and the a,e conformations." @default.
- W2071887682 created "2016-06-24" @default.
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- W2071887682 creator A5090817340 @default.
- W2071887682 date "2006-01-01" @default.
- W2071887682 modified "2023-09-23" @default.
- W2071887682 title "1, 2-, 1, 3- and 1, 4-Cyclohexanedicarboxylates of Cd and Mn with chain and layered structures" @default.
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- W2071887682 doi "https://doi.org/10.1039/b512843a" @default.
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