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- W2071893661 abstract "Abstract The investigation of chromatograhic systems with silica and mobile phases consisting of ethyl acetate and weakly soluble polar components ethylene glycol, triethylene glycol and formamide has shown that mixed mechanism of sorption is possible. When the solubility of the polar component is good, as in case of methanol, the retentions observed are typical of adsorption chromatography. When ethylene glycol, which has limited solubility, is used as the mobile phase component, a liquid stationary phase consisting mainly of polar solvent is formed in the pores of silica. This leads to a mixed mechanism of retention, selectivity changes and improvement of the peak shape. The formation of a liquid stationary phase both from saturated and unsaturated solutions is observed." @default.
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- W2071893661 date "1991-08-01" @default.
- W2071893661 modified "2023-09-27" @default.
- W2071893661 title "Adsorption and partition mode in high-performance liquid chromatography of highly polar solutes on silica" @default.
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- W2071893661 doi "https://doi.org/10.1016/s0021-9673(01)95920-5" @default.
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