Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071896144> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2071896144 endingPage "3379" @default.
- W2071896144 startingPage "3373" @default.
- W2071896144 abstract "The matrix isolation technique, combined with infrared spectroscopy and theoretical calculations, has been used to investigate VCl4, as well as its reactions with CH3OH and its isotopomers. The infrared spectrum of VCl4 in solid argon showed an intense doublet at 474 and 501 cm-1, which is indicative of a splitting of the triply degenerate stretching mode in Td symmetry due to Jahn−Teller distortion. Density functional theory (DFT) calculations (UB3LYP/6-311++g(d,2p)) reproduced this splitting very well. The calculated structure had four equal V−Cl bonds, but with two Cl−V−Cl angles equal to 110.8° and two angles equal to 106.9°. Using twin-jet deposition, the initial intermediate in the reaction of VCl4 with CH3OH was identified as a 1:1 molecular complex, characterized by perturbations to the V−Cl, C−O, and O−H stretching modes. This complex was destroyed by near-UV irradiation, producing the novel Cl3VOCH3 species and cage-paired HCl. Merged-jet co-deposition of CH3OH and VCl4, with a room-temperature reaction zone, led to almost-complete conversion to Cl3VOCH3. This species was identified by use of isotopic labeling, the observation of HCl as an additional reaction product, and by comparison to DFT calculations. In addition, a large yield of CH3Cl was observed." @default.
- W2071896144 created "2016-06-24" @default.
- W2071896144 creator A5018166558 @default.
- W2071896144 creator A5044377317 @default.
- W2071896144 date "2004-03-19" @default.
- W2071896144 modified "2023-09-23" @default.
- W2071896144 title "Matrix-Isolation Infrared and Theoretical Study of the Reaction of VCl<sub>4</sub> with CH<sub>3</sub>OH" @default.
- W2071896144 cites W1970653515 @default.
- W2071896144 cites W1973994610 @default.
- W2071896144 cites W1991744118 @default.
- W2071896144 cites W1996493010 @default.
- W2071896144 cites W2013540332 @default.
- W2071896144 cites W2020792165 @default.
- W2071896144 cites W2026006693 @default.
- W2071896144 cites W2026010116 @default.
- W2071896144 cites W2028300623 @default.
- W2071896144 cites W2028337811 @default.
- W2071896144 cites W2033002525 @default.
- W2071896144 cites W2048347199 @default.
- W2071896144 cites W2050748214 @default.
- W2071896144 cites W2052992198 @default.
- W2071896144 cites W2065140582 @default.
- W2071896144 cites W2321183929 @default.
- W2071896144 cites W2327168569 @default.
- W2071896144 cites W2465272958 @default.
- W2071896144 cites W3005164052 @default.
- W2071896144 doi "https://doi.org/10.1021/jp037726c" @default.
- W2071896144 hasPublicationYear "2004" @default.
- W2071896144 type Work @default.
- W2071896144 sameAs 2071896144 @default.
- W2071896144 citedByCount "6" @default.
- W2071896144 countsByYear W20718961442013 @default.
- W2071896144 countsByYear W20718961442015 @default.
- W2071896144 countsByYear W20718961442018 @default.
- W2071896144 crossrefType "journal-article" @default.
- W2071896144 hasAuthorship W2071896144A5018166558 @default.
- W2071896144 hasAuthorship W2071896144A5044377317 @default.
- W2071896144 hasConcept C106487976 @default.
- W2071896144 hasConcept C113196181 @default.
- W2071896144 hasConcept C120665830 @default.
- W2071896144 hasConcept C121332964 @default.
- W2071896144 hasConcept C127124265 @default.
- W2071896144 hasConcept C134121241 @default.
- W2071896144 hasConcept C147597530 @default.
- W2071896144 hasConcept C152365726 @default.
- W2071896144 hasConcept C153642686 @default.
- W2071896144 hasConcept C158355884 @default.
- W2071896144 hasConcept C178790620 @default.
- W2071896144 hasConcept C185592680 @default.
- W2071896144 hasConcept C191897082 @default.
- W2071896144 hasConcept C192562407 @default.
- W2071896144 hasConcept C2777896788 @default.
- W2071896144 hasConcept C32909587 @default.
- W2071896144 hasConcept C43617362 @default.
- W2071896144 hasConceptScore W2071896144C106487976 @default.
- W2071896144 hasConceptScore W2071896144C113196181 @default.
- W2071896144 hasConceptScore W2071896144C120665830 @default.
- W2071896144 hasConceptScore W2071896144C121332964 @default.
- W2071896144 hasConceptScore W2071896144C127124265 @default.
- W2071896144 hasConceptScore W2071896144C134121241 @default.
- W2071896144 hasConceptScore W2071896144C147597530 @default.
- W2071896144 hasConceptScore W2071896144C152365726 @default.
- W2071896144 hasConceptScore W2071896144C153642686 @default.
- W2071896144 hasConceptScore W2071896144C158355884 @default.
- W2071896144 hasConceptScore W2071896144C178790620 @default.
- W2071896144 hasConceptScore W2071896144C185592680 @default.
- W2071896144 hasConceptScore W2071896144C191897082 @default.
- W2071896144 hasConceptScore W2071896144C192562407 @default.
- W2071896144 hasConceptScore W2071896144C2777896788 @default.
- W2071896144 hasConceptScore W2071896144C32909587 @default.
- W2071896144 hasConceptScore W2071896144C43617362 @default.
- W2071896144 hasIssue "16" @default.
- W2071896144 hasLocation W20718961441 @default.
- W2071896144 hasOpenAccess W2071896144 @default.
- W2071896144 hasPrimaryLocation W20718961441 @default.
- W2071896144 hasRelatedWork W1569783553 @default.
- W2071896144 hasRelatedWork W1968352773 @default.
- W2071896144 hasRelatedWork W1975050511 @default.
- W2071896144 hasRelatedWork W1990644624 @default.
- W2071896144 hasRelatedWork W1995946577 @default.
- W2071896144 hasRelatedWork W2028368664 @default.
- W2071896144 hasRelatedWork W2031985047 @default.
- W2071896144 hasRelatedWork W2051765290 @default.
- W2071896144 hasRelatedWork W2066385684 @default.
- W2071896144 hasRelatedWork W2087842270 @default.
- W2071896144 hasVolume "108" @default.
- W2071896144 isParatext "false" @default.
- W2071896144 isRetracted "false" @default.
- W2071896144 magId "2071896144" @default.
- W2071896144 workType "article" @default.