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- W2071918059 abstract "The complex [Rh(NBD)(PPh3)2]BF4 catalyzes the selective hydrogenation of phenylacetylene to styrene. In dichloromethane solution at 25°C, selectivities close to 80% are achieved. The reaction is first order in catalyst and substrate, and second order in hydrogen pressure, while the addition of triphenylphosphine inhibits the reduction. The mechanism deduced for this hydrogenation, on the basis of the above mentioned kinetic results, suggests that the reduction of the diolefin of the catalyst does not occur during the hydrogenation of the alkyne." @default.
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- W2071918059 date "1998-01-01" @default.
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- W2071918059 title "Kinetic studies on the selective hydrogenation of phenylacetylene catalyzed by [Rh(NBD)(PPh3)2]BF4 (NBD=2,5-norbornadiene)" @default.
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- W2071918059 doi "https://doi.org/10.1016/s0022-328x(97)00426-9" @default.
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