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• W2071921323 abstract "This paper reports the spectroscopic properties of cerium- and praseodymium-doped alkali metal yttrium double phosphates, M3Y(PO4)2:Pr3+, Ce3+; M = Na, Rb. These phosphates were obtained by a solid state reaction between lanthanide phosphate hydrates and M3PO4. The absorption, reflection, emission and excitation spectra were measured at room temperature, 77 and 4 K in the IR-vis-ultraviolet (UV) range. For both the Ce3+- and Pr3+-doped double phosphates, the 4fN↔4fN−15d transitions were detected. For the Pr3+-doped double phosphates, the 4f–4f transitions from the 3H4 ground manifold were analyzed. The low temperature 3H4→3P0 absorption spectra were used to characterize the structural modifications between the sodium and rubidium salts. For the Ce3+-doped double phosphate, the strong blue 5d1→4f1 emission band splits into two components due to the 2F5/2−2F7/2 splitting of the 4f1 configuration. Intense emission occurs mainly from the 3P0 level at high dopant concentrations, since the 1D2 emission is strongly quenched but was detected at the 2 mol% doping level. In spite of the forbidden 4f–4f character, the 3P0 transitions have very short decay times, of the order of one μs. Dynamics of the excited states will be discussed based on the decay times and selective excited emission." @default.
• W2071921323 created "2016-06-24" @default.
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• W2071921323 date "2004-10-01" @default.
• W2071921323 modified "2023-10-18" @default.
• W2071921323 title "Optical spectroscopy of yttrium double phosphates doped by cerium and praseodymium ions" @default.
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• W2071921323 doi "https://doi.org/10.1016/j.jallcom.2004.03.062" @default.
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