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• W2071940009 abstract "Electronic structures of perovskite oxides of SrMn${}_{1ensuremath{-}x}$Mo${}_{x}$O${}_{3}$ in the Mo-rich regime ($xensuremath{geqslant}0.5$) have been investigated by employing soft x-ray absorption spectroscopy (XAS). Mn $2p$ XAS spectra of SrMn${}_{1ensuremath{-}x}$Mo${}_{x}$O${}_{3}$ indicate that the valence states of Mn ions are divalent and that they remain nearly unchanged for $xensuremath{geqslant}0.5$. On the other hand, the Mo $3p$ XAS spectra of SrMn${}_{1ensuremath{-}x}$Mo${}_{x}$O${}_{3}$ show some changes, suggesting that the valence states of Mo ions decrease with increasing $x$ for $xensuremath{geqslant}0.5$. These conclusions are supported by the unoccupied Mn $3d$ and Mo $4d$ states, observed experimentally in the O $1s$ XAS spectra of SrMn${}_{1ensuremath{-}x}$Mo${}_{x}$O${}_{3}$." @default.
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• W2071940009 date "2011-02-24" @default.
• W2071940009 modified "2023-10-18" @default.
• W2071940009 title "Soft x-ray absorption spectroscopy study of Mo-rich SrMn1−xMoxO3(x⩾0.5)" @default.
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• W2071940009 doi "https://doi.org/10.1103/physrevb.83.073103" @default.
• W2071940009 hasPublicationYear "2011" @default.
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