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- W2071954080 abstract "[structure] The deracemization of 3-nonyl-3,4-epoxybut-1-ene with Pd(0) in the presence of chiral ligands using p-methoxybenzyl alcohol as a nucleophile proceeds regio- and enantioselectively to form the monoprotected vinylglycidol in 99% ee. This chiral building block was converted in seven steps to (-)-malyngolide, an antibiotic showing significant activity against Mycobacterium smegmatis and Streptococcus pyogenes. An interesting aspect involves controlling the diastereoselectivity of protonation of an enolate via a distal hydroxyl group." @default.
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- W2071954080 date "2001-04-03" @default.
- W2071954080 modified "2023-09-27" @default.
- W2071954080 title "ChemInform Abstract: Asymmetric Synthesis of Quaternary Centers. Total Synthesis of (-)-Malyngolide." @default.
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- W2071954080 doi "https://doi.org/10.1002/chin.200114244" @default.
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