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- W2071980094 abstract "Abstract A marked increase of the catalytic hydrogen evolution due to the presence of gelatine or aminoacids added to the Cu(II)-Tu-2M H2SO4 system (Tu-thiourea) is indicated by polarographic studies. Spectral and polarographic studies of the Cu(II)-Tu-gelatine(aminoacid)-2M H2SO4 system with oxidants like Ce(IV) and H2O2 added have demonstrated, that the catalytic hydrogen evolution is due to the presence of mixed thiourea-aminoacid Cu(II) complexes. Differences in the mechanism of Ce(IV) and H2O2 oxidation of mixed thiourea-aminoacid Cu(I) complexes are indicated. A mixed ligand Cu(I) complexes {Cu2[(NH2)2(NH)2C2S2] [(NH2)2 CS]2 (C2NO2H5)2}·6H2O was isolated." @default.
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- W2071980094 date "1977-01-01" @default.
- W2071980094 modified "2023-09-27" @default.
- W2071980094 title "Polarographic and spectral studies of copper(I) oxidation in Cu(II)-thiourea-aminoacid-2M H2SO4 systems" @default.
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- W2071980094 doi "https://doi.org/10.1016/0022-1902(77)80116-4" @default.
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