Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072005462> ?p ?o ?g. }
- W2072005462 endingPage "9485" @default.
- W2072005462 startingPage "9475" @default.
- W2072005462 abstract "Whereas encapsulation of functional groups at the core of dendrimers is well-understood, very little is known about their intermediate layers or even the periphery. Here we report on a systematic investigation of every layer of dendrimers by incorporating a single ferrocene unit in well-defined locations in dendrons. Site-specific incorporation of the ferrocene unit was achieved by utilizing the dendrimer sequencing methodology. We show here that the redox potential values of ferrocene at intermediate layers were remarkably different from those at the core and the periphery. Although redox potential values were location-dependent, no significant change in the rate of heterogeneous electron transfer (k(0)) was observed with respect to locations. This was attributed to the possibility that free rotation of dendrimer nullifies the distance between the electrode and ferrocene unit. Finally, we also show that no Faradaic current was observed for the amphiphilic assemblies of these dendrons, whereas the same dendron did exhibit significant Faradaic current in nonassembling solvent environments." @default.
- W2072005462 created "2016-06-24" @default.
- W2072005462 creator A5007792382 @default.
- W2072005462 creator A5026543983 @default.
- W2072005462 creator A5059887581 @default.
- W2072005462 creator A5089082573 @default.
- W2072005462 date "2009-11-12" @default.
- W2072005462 modified "2023-10-01" @default.
- W2072005462 title "Site-Specific Installation and Study of Electroactive Units in Every Layer of Dendrons" @default.
- W2072005462 cites W1567174955 @default.
- W2072005462 cites W1773787764 @default.
- W2072005462 cites W1963687146 @default.
- W2072005462 cites W1967264591 @default.
- W2072005462 cites W1968869310 @default.
- W2072005462 cites W1969208782 @default.
- W2072005462 cites W1969726555 @default.
- W2072005462 cites W1969901888 @default.
- W2072005462 cites W1973538689 @default.
- W2072005462 cites W1973718137 @default.
- W2072005462 cites W1983007125 @default.
- W2072005462 cites W1988531263 @default.
- W2072005462 cites W1992226382 @default.
- W2072005462 cites W1993881057 @default.
- W2072005462 cites W1993943187 @default.
- W2072005462 cites W1998506791 @default.
- W2072005462 cites W1999343253 @default.
- W2072005462 cites W2002903271 @default.
- W2072005462 cites W2003563163 @default.
- W2072005462 cites W2008708280 @default.
- W2072005462 cites W2013336137 @default.
- W2072005462 cites W2013436288 @default.
- W2072005462 cites W2017681223 @default.
- W2072005462 cites W2019102652 @default.
- W2072005462 cites W2022313727 @default.
- W2072005462 cites W2026771811 @default.
- W2072005462 cites W2029598925 @default.
- W2072005462 cites W2031490852 @default.
- W2072005462 cites W2031510230 @default.
- W2072005462 cites W2032763020 @default.
- W2072005462 cites W2033134995 @default.
- W2072005462 cites W2034353053 @default.
- W2072005462 cites W2035821461 @default.
- W2072005462 cites W2037282446 @default.
- W2072005462 cites W2039645139 @default.
- W2072005462 cites W2040008477 @default.
- W2072005462 cites W2040928641 @default.
- W2072005462 cites W2043192160 @default.
- W2072005462 cites W2049723495 @default.
- W2072005462 cites W2050809513 @default.
- W2072005462 cites W2053035464 @default.
- W2072005462 cites W2058490945 @default.
- W2072005462 cites W2059026530 @default.
- W2072005462 cites W2059148938 @default.
- W2072005462 cites W2065263347 @default.
- W2072005462 cites W2069701108 @default.
- W2072005462 cites W2072192656 @default.
- W2072005462 cites W2072327463 @default.
- W2072005462 cites W2073337400 @default.
- W2072005462 cites W2076247161 @default.
- W2072005462 cites W2076436711 @default.
- W2072005462 cites W2079648403 @default.
- W2072005462 cites W2080575130 @default.
- W2072005462 cites W2082347774 @default.
- W2072005462 cites W2083059967 @default.
- W2072005462 cites W2084565048 @default.
- W2072005462 cites W2086528484 @default.
- W2072005462 cites W2088036062 @default.
- W2072005462 cites W2091480194 @default.
- W2072005462 cites W2102586146 @default.
- W2072005462 cites W2109199526 @default.
- W2072005462 cites W2113602264 @default.
- W2072005462 cites W2145662716 @default.
- W2072005462 cites W2149100886 @default.
- W2072005462 cites W2158508585 @default.
- W2072005462 cites W2158702474 @default.
- W2072005462 cites W2167201747 @default.
- W2072005462 cites W2171660150 @default.
- W2072005462 cites W2500266776 @default.
- W2072005462 cites W2950068968 @default.
- W2072005462 cites W2950388682 @default.
- W2072005462 cites W2950608203 @default.
- W2072005462 cites W2950974896 @default.
- W2072005462 cites W2951901527 @default.
- W2072005462 cites W2952513104 @default.
- W2072005462 cites W4214530537 @default.
- W2072005462 cites W4234786030 @default.
- W2072005462 cites W2088400770 @default.
- W2072005462 doi "https://doi.org/10.1021/jo902109u" @default.
- W2072005462 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2795052" @default.
- W2072005462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19905006" @default.
- W2072005462 hasPublicationYear "2009" @default.
- W2072005462 type Work @default.
- W2072005462 sameAs 2072005462 @default.
- W2072005462 citedByCount "12" @default.
- W2072005462 countsByYear W20720054622012 @default.
- W2072005462 countsByYear W20720054622014 @default.
- W2072005462 countsByYear W20720054622015 @default.
- W2072005462 countsByYear W20720054622017 @default.