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- W2072007203 abstract "Thermal decomposition of [Rh(CO)2Cl]2 was studied on two different Al2O3 substrates prepared by oxidation of Al(100) with O2. Treatment of Al(100) with 1700 L O2 at 200°C produced an 18 Å Al2O3 film. Oxidation of Al(100) with 4 × 10−3 Torr of O2 595°C formed an oxide overlayer greater than 80 Å thick. Thermal decomposition of [Rh(CO)2Cl]2 on the two Al2O3 films was monitored with TPD, XPS, and AES. TPD data obtained during thermal decomposition of [Rh(CO)2Cl]2 showed a marked difference in the CO evolution profiles on the two different substrates. The maximum in CO evolution varied by 125°C on the two samples. CO chemisorption measurements showed the formation of 120 Å Rh particles on the thin (18 Å) Al2O3 support and 20 Å Rh particles on the thick oxide overlayer. XPS data indicated that Rho particles were present in both cases. The results suggest that structural differences in the two supports control the decomposition mechanism and therefore the resultant Rh particle size." @default.
- W2072007203 created "2016-06-24" @default.
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- W2072007203 date "1988-01-01" @default.
- W2072007203 modified "2023-09-23" @default.
- W2072007203 title "Interaction of [Rh(CO)2Cl]2 with O2 oxidized Al(100): Effect of Al2O3 preparation on [Rh(CO)2Cl]2 decomposition" @default.
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- W2072007203 doi "https://doi.org/10.1016/0039-6028(88)90919-3" @default.
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