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- W2072024118 abstract "The crystal structure of the α-form of poly(l-lactide) was analyzed by the linked-atom least-squares refinements for the X-ray fiber diffraction data. The space group was orthorhombic P212121, and the unit cell contained the antiparallel two chains. The chain conformation was the 2-fold s(15*2/7) helix distorted periodically from the regular s(3*10/7) helix. The ester groups were deformed from the planar trans conformation. Potential energy calculations suggested that the periodic chain distortion resulted from the impartial stress distribution due to the interchain interactions." @default.
- W2072024118 created "2016-06-24" @default.
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- W2072024118 date "2003-10-04" @default.
- W2072024118 modified "2023-10-13" @default.
- W2072024118 title "Helix Distortion and Crystal Structure of the α-Form of Poly(<scp>l</scp>-lactide)" @default.
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- W2072024118 doi "https://doi.org/10.1021/ma0348674" @default.
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