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- W2072040667 abstract "This chapter presents the chemistry of phanes bridged by group 14 heavy elements. The degree of through-bond interaction in [2.2]paracyclophane 12 bridged by two Si–Si bonds is the greatest among the series of the cyclophanes bridged by Group 14 elements. Prior to the studies on phanes, a new ring system, 3,4,7,8-tetrasilacycloocta-1,5-diyne, composed of two Si–Si σ and two C≡C π bonds is studied. The Various types of phanes have been prepared and structures and reactions have been investigated in detail. In all the [2.2]paracyclophanes, the bridging bonds are somewhat elongated from the normal bond lengths, and the benzene rings are distorted into boat conformations. [2.2]metacyclophane (2), relative conformations of two aromatic rings in [2.2](2,5)heterophanes have been studied in detail by NMR. [2.2]Paracyclophanes bridged by Group 14 heavy elements try to keep interplanar distances constant to the value for graphite, regardless of any increase in the bridging bond lengths." @default.
- W2072040667 created "2016-06-24" @default.
- W2072040667 creator A5048376516 @default.
- W2072040667 date "2000-01-01" @default.
- W2072040667 modified "2023-10-15" @default.
- W2072040667 title "Phanes bridged by group 14 heavy elements" @default.
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- W2072040667 doi "https://doi.org/10.1016/s0898-8838(00)50008-7" @default.
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