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- W2072062010 abstract "Radiolytically produced normal methyl radicals are stabilized on solid surfaces at room temperature for the first time. This radical can be stabilized on both basic and neutral alumina but not on acidic alumina. Failure to observe the radical on other acidic surfaces such as silica gel and porous Vycor glass at room temperature suggests that the radical is perturbed under these conditions. A line broadening effect observed for this species at liquid nitrogen temperature is not found for methyl radicals on either silica gel or porous Vycor glass surfaces. This observation together with the low reactivity of the radical towards various additives implies that the radical is immobilized at an inaccessible site on the alumina surface." @default.
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- W2072062010 date "1981-07-01" @default.
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- W2072062010 title "On the catalytic reactivity of solid surfaces. II. Stabilization of radiolytically produced methyl radicals at 300 K" @default.
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- W2072062010 doi "https://doi.org/10.1016/0378-5963(81)90121-5" @default.
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