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- W2072062129 abstract "Matrix elements of the Hamiltonian for doublet states of rotating molecules in a Zeeman field are calculated in the uncoupled (J, S) representation. The energy matrix assumes a simple form for near-symmetric rotors, when the magnetic interactions are diagonal in K. Measurements of the Zeeman effect in the (100)-(000) band of the 2A2 ← 2B1 transition of chlorine dioxide are reported at fields up to 14 kG. These observations establish that the spin-rotation coupling constants in the 2A2 state are: a0 = −0.0149 ± 0.0018, a = −0.0306 ± 0.0016 cm−1." @default.
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- W2072062129 date "1972-08-01" @default.
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- W2072062129 title "Theory of the Zeeman effect in doublet states of a near-symmetric rotor: Application to the 2A2 ← 2B1 transition of ClO2" @default.
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- W2072062129 doi "https://doi.org/10.1016/0022-2852(72)90017-3" @default.
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