FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072088396> ?p ?o ?g. }

• W2072088396 endingPage "359" @default.
• W2072088396 startingPage "351" @default.
• W2072088396 abstract "Proton decoupled deuterium NMR spectra of oriented bilayers made of DMPC and 30 mol % deuterated cholesterol acquired at 76.8 MHz (30°C) have provided a set of very accurate quadrupolar splitting for eight C-D bonds of cholesterol. Due to the new precision of the experimental data, the original analysis by Dufourc et al. (1984. Biochemistry. 23:6062–6071) had to be reconsidered. We performed a systematic study of the influence on the precision and uniqueness of the data-fitting procedure of: (i) the coordinates derived from x-ray, neutron scattering, or force field-minimized structures, (ii) internal mobility, (iii) the axial symmetry hypothesis, and (iv) the knowledge of some quadrupolar splitting assignments. Good agreement between experiment and theory could be obtained only with the neutron scattering structure, for which both axial symmetry hypothesis and full order parameter matrix analysis gave satisfactory results. Finally, this work revealed an average orientation of cholesterol slightly different from those previously published and, most importantly, a molecular order parameter equal to 0.95 ± 0.01, instead of 0.79 ± 0.03 previously found for the same system at 30°C. Temperature dependence in the 20–50°C range shows a constant average orientation and a monotonous decrease of cholesterol Smol, with a slope of −0.0016 K−1. A molecular order parameter of 0.89 ± 0.01 at 30°C was determined for a DMPC/16 mol % of cholesterol." @default.
• W2072088396 created "2016-06-24" @default.
• W2072088396 creator A5017170472 @default.
• W2072088396 creator A5025088152 @default.
• W2072088396 creator A5042818274 @default.
• W2072088396 creator A5045711795 @default.
• W2072088396 creator A5048584112 @default.
• W2072088396 creator A5059037162 @default.
• W2072088396 creator A5075926341 @default.
• W2072088396 date "1999-01-01" @default.
• W2072088396 modified "2023-10-15" @default.
• W2072088396 title "Cholesterol Orientation and Dynamics in Dimyristoylphosphatidylcholine Bilayers: A Solid State Deuterium NMR Analysis" @default.
• W2072088396 cites W1600382534 @default.
• W2072088396 cites W1966339391 @default.
• W2072088396 cites W1979173334 @default.
• W2072088396 cites W1982108116 @default.
• W2072088396 cites W1982863203 @default.
• W2072088396 cites W1985596412 @default.
• W2072088396 cites W1986275658 @default.
• W2072088396 cites W1990587059 @default.
• W2072088396 cites W2001355446 @default.
• W2072088396 cites W2006996972 @default.
• W2072088396 cites W2009480358 @default.
• W2072088396 cites W2011664200 @default.
• W2072088396 cites W2013041903 @default.
• W2072088396 cites W2022593894 @default.
• W2072088396 cites W2026614994 @default.
• W2072088396 cites W2027217260 @default.
• W2072088396 cites W2028665207 @default.
• W2072088396 cites W2038252923 @default.
• W2072088396 cites W2039337052 @default.
• W2072088396 cites W2049709847 @default.
• W2072088396 cites W2054413392 @default.
• W2072088396 cites W2058532748 @default.
• W2072088396 cites W2064845310 @default.
• W2072088396 cites W2068636421 @default.
• W2072088396 cites W2071948808 @default.
• W2072088396 cites W2086687678 @default.
• W2072088396 cites W2090333154 @default.
• W2072088396 cites W2095108329 @default.
• W2072088396 cites W2095354007 @default.
• W2072088396 cites W2109260970 @default.
• W2072088396 cites W2992759440 @default.
• W2072088396 cites W4255370921 @default.
• W2072088396 doi "https://doi.org/10.1016/s0006-3495(99)77202-4" @default.
• W2072088396 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/1302524" @default.
• W2072088396 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9876147" @default.
• W2072088396 hasPublicationYear "1999" @default.
• W2072088396 type Work @default.
• W2072088396 sameAs 2072088396 @default.
• W2072088396 citedByCount "91" @default.
• W2072088396 countsByYear W20720883962012 @default.
• W2072088396 countsByYear W20720883962013 @default.
• W2072088396 countsByYear W20720883962014 @default.
• W2072088396 countsByYear W20720883962015 @default.
• W2072088396 countsByYear W20720883962016 @default.
• W2072088396 countsByYear W20720883962017 @default.
• W2072088396 countsByYear W20720883962018 @default.
• W2072088396 countsByYear W20720883962019 @default.
• W2072088396 countsByYear W20720883962020 @default.
• W2072088396 countsByYear W20720883962021 @default.
• W2072088396 countsByYear W20720883962022 @default.
• W2072088396 countsByYear W20720883962023 @default.
• W2072088396 crossrefType "journal-article" @default.
• W2072088396 hasAuthorship W2072088396A5017170472 @default.
• W2072088396 hasAuthorship W2072088396A5025088152 @default.
• W2072088396 hasAuthorship W2072088396A5042818274 @default.
• W2072088396 hasAuthorship W2072088396A5045711795 @default.
• W2072088396 hasAuthorship W2072088396A5048584112 @default.
• W2072088396 hasAuthorship W2072088396A5059037162 @default.
• W2072088396 hasAuthorship W2072088396A5075926341 @default.
• W2072088396 hasBestOaLocation W20720883961 @default.
• W2072088396 hasConcept C104015590 @default.
• W2072088396 hasConcept C113196181 @default.
• W2072088396 hasConcept C120665830 @default.
• W2072088396 hasConcept C121332964 @default.
• W2072088396 hasConcept C147597530 @default.
• W2072088396 hasConcept C152568617 @default.
• W2072088396 hasConcept C16345878 @default.
• W2072088396 hasConcept C184779094 @default.
• W2072088396 hasConcept C185592680 @default.
• W2072088396 hasConcept C191486275 @default.
• W2072088396 hasConcept C2524010 @default.
• W2072088396 hasConcept C33923547 @default.
• W2072088396 hasConcept C41999313 @default.
• W2072088396 hasConcept C43617362 @default.
• W2072088396 hasConcept C46141821 @default.
• W2072088396 hasConcept C54516573 @default.
• W2072088396 hasConcept C58364064 @default.
• W2072088396 hasConcept C59593255 @default.
• W2072088396 hasConcept C62520636 @default.
• W2072088396 hasConcept C8010536 @default.
• W2072088396 hasConceptScore W2072088396C104015590 @default.
• W2072088396 hasConceptScore W2072088396C113196181 @default.
• W2072088396 hasConceptScore W2072088396C120665830 @default.
• W2072088396 hasConceptScore W2072088396C121332964 @default.
• W2072088396 hasConceptScore W2072088396C147597530 @default.
• W2072088396 hasConceptScore W2072088396C152568617 @default.

• next