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- W2072091949 abstract "Photo-oxidative coupling polymerization of methoxy acetonitrile was carried out by using organic peroxide as an oxidizing agent under UV light irradiation at ambient temperature. The acetonitrile gave a homopolymer with a molecular weight of about 1000-1600 in moderate yield. 1H-NMR and ESR spectra demonstrated the production of the polymer with the structure of 1,1-disubstituted polymethylene through a methoxycyanomethyl radical intermediate. It was also found that the polymer easily produced unpaired electrons in the structure only by heating and it initiated the polymerization of methyl methacrylate above 70°C. In addition, the acetonitrile also afforded a copolymer with diphenylmethane by the coupling polymerization." @default.
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- W2072091949 date "1993-01-01" @default.
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- W2072091949 title "Photo-oxidative coupling polymerization of methoxy acetonitrile and thermal behavior of the polymer obtained" @default.
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- W2072091949 doi "https://doi.org/10.1002/pi.4990320113" @default.
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