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- W2072125743 abstract "The controllable synthesis of nanomaterials with unique morphologies and sizes has attracted increasing interest because of the shape-dependent properties of the nanomaterials. In this article, we report the synthesis of the new 6-fold-symmetrical AlN hierarchical nanostructures including urchinlike and flowerlike ones assembled by AlN nanoneedles through the chemical reaction between AlCl3 and NH3 with the vaporization temperature of AlCl3 between 120 and 165 °C and the reaction temperature higher than 1050 °C. The morphologies, sizes, and densities of the AlN nanostructures could be controllably modulated by changing the reaction temperature and the vapor pressure of AlCl3. The formation mechanism of the AlN hierarchical nanostructures has been discussed on the basis of the change in the AlCl3 vapor pressure and the morphological evolution of the intermediate products. The shape-dependent properties of the AlN products have been observed, and the urchinlike nanostructures showed better optical and field-emission properties in comparison with the flowerlike ones. These results indicate the potential applications of the 6-fold-symmetrical AlN hierarchical nanostructures in optoelectronic and field-emission devices." @default.
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- W2072125743 date "2009-02-13" @default.
- W2072125743 modified "2023-09-22" @default.
- W2072125743 title "6-Fold-Symmetrical AlN Hierarchical Nanostructures: Synthesis and Field-Emission Properties" @default.
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- W2072125743 doi "https://doi.org/10.1021/jp811484r" @default.
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