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- W2072156632 abstract "Crystals of a C60 1:1 solvate (I-centered cubic, a = 23.284(2) Å) were grown by evaporating solutions of C60 in H2CCl2 at room temperature. Solvate crystals are not air stable and spontaneously transform into a hexagonal polymorph of C60 (a = 10.044(5) Å, c = 16.404(8) Å, c/a = 1.633(2)) when extracted from the mother liquor at room temperature. Although solvate formation entails almost no volume change, desolvation enthalpy (59.2 kJ/mol of solvent) is found to be about twice as high as sublimation enthalpy for pure H2CCl2." @default.
- W2072156632 created "2016-06-24" @default.
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- W2072156632 date "2001-03-17" @default.
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- W2072156632 title "Solid-State Studies on a Cubic 1:1 Solvate of C<sub>60</sub> Grown from Dichloromethane and Leading to Another Hexagonal C<sub>60</sub> Polymorph" @default.
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- W2072156632 doi "https://doi.org/10.1021/cm001212y" @default.
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