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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2072192330> ?p ?o ?g. }

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• W2072192330 startingPage "5062" @default.
• W2072192330 abstract "A novel Au-catalyzed homogeneous oxidative C−O bond-forming reaction involving a Au(I)/Au(III) catalytic cycle is developed. Mechanistic studies reveal the involvement of a unique intramolecular carboxy migration. From readily available propargylic benzoates, this chemistry allows efficient access to captodative alkenes and dienones, demonstrating the synthetic potential of incorporating Au(I)/Au(III) catalytic cycles into contemporary Au chemistry. The unique reactivity and the mechanistic insights would help open a new research area in gold catalysis." @default.
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• W2072192330 date "2009-03-20" @default.
• W2072192330 modified "2023-10-11" @default.
• W2072192330 title "Gold-Catalyzed Homogeneous Oxidative C−O Bond Formation: Efficient Synthesis of 1-Benzoxyvinyl Ketones" @default.
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• W2072192330 doi "https://doi.org/10.1021/ja901048w" @default.
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