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- W2072205035 abstract "The selective benzoylation of monosaccharides can be accomplished, with little or no anomerisation, to give synthetically useful benzoate derivatives. Thus, α-D-glucopyranose and α-D-mannopyranose 1,2,3,6-tetrabenzoates, β-L-arabinopyranose 1,2,3-tribenzoate, and α-D-xylopyranose 1,2,4-tribenzoate were prepared. Circular dichroism measurements have been used to confirm the structures of some of these benzoates. Attempted azide displacement of the sulphonate group in 1,2,3,6-tetra-O-benzoyl-4-O-methanesulphonyl-α-D-glucopyranose resulted in rearrangement to give 1,4-anhydro-β-D-galactopyranose tribenzoate, but normal displacement occurred for 1,2,3-tri-O-benzoyl-4-O-methanesulphony]-β-L-arabinopyranose." @default.
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- W2072205035 date "1975-08-01" @default.
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- W2072205035 title "The selective benzoylation of monosaccharides" @default.
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- W2072205035 doi "https://doi.org/10.1016/s0008-6215(00)83970-1" @default.
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