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• W2072213233 endingPage "700" @default.
• W2072213233 startingPage "694" @default.
• W2072213233 abstract "BaZr(0.9 − x)CexY(0.1 − y)CoyO(3 − δ) (with x = 0 and 0.2; y = 0.01; 0.02; 0.05) and BaZr(0.9 − x)CexY(0.1 − y)NiyO(3 − δ) (with x = 0 and 0.2; y = 0.01; 0.02) compounds have been synthesized by solid state reaction at 1400 °C and obtained as dense pellets after sintering at 1450 °C. Cobalt or nickel doping reduces the sintering temperature by about 250 °C. The samples are stable in a CO2 rich atmosphere at 600 °C but the 5% B site Co doped samples are aging in wet atmosphere. The conductivity has been measured for the 1 and 2% doped samples (both cobalt and nickel), in different wet atmospheres and compared to the undoped compounds. The ionic and p-type conductivities have been determined, as well as the activation energy in wet reducing atmospheres, in which protonic conduction is dominant. A decrease of the ionic conductivity is noticeable for the cobalt or nickel doped barium zirconate (x = 0), while not for cobalt or nickel solid solution of barium cerate and zirconate (x = 0.2)." @default.
• W2072213233 created "2016-06-24" @default.
• W2072213233 creator A5020490246 @default.
• W2072213233 creator A5082716634 @default.
• W2072213233 date "2010-06-03" @default.
• W2072213233 modified "2023-09-26" @default.
• W2072213233 title "Enhanced sintering and conductivity study of cobalt or nickel doped solid solution of barium cerate and zirconate" @default.
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• W2072213233 doi "https://doi.org/10.1016/j.ssi.2010.04.007" @default.
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