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• W2072237266 abstract "Using a two-dimensional self-consistent field theory, we investigate the interaction between two planar surfaces where (1) each surface is grafted with both A and B homopolymers and (2) one surface is coated with end-grafted A's and the other is coated with end-grafted B's. The chains are grafted at low densities and the B polymers are chosen to be solvophobic. We vary the solvent affinity of the A chains and the interaction between the A and B monomers. We determine the morphology of the layers and the energy of interaction as the layers are compressed. The energy of interaction versus distance profiles show a wide region of attraction as the surfaces are brought together. This attractive interaction is due to the self-assembled structures that appear at low grafting densities in poor solvents. The properties of the attraction can be tailored, as we demonstrate in a simple scaling picture. Our findings indicate that fine control over the pair interaction function of coated colloidal particles can be gained through grafting mixtures of homopolymers." @default.
• W2072237266 created "2016-06-24" @default.
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• W2072237266 date "1996-01-01" @default.
• W2072237266 modified "2023-10-13" @default.
• W2072237266 title "Interactions between Polymer-Coated Surfaces in Poor Solvents. 1. Surfaces Grafted with A and B Homopolymers" @default.
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• W2072237266 doi "https://doi.org/10.1021/ma9608129" @default.
• W2072237266 hasPublicationYear "1996" @default.
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