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- W2072265937 abstract "A full account of the total synthesis of (±)-maistemonine, (±)-stemonamide, and (±)-isomaistemonine is presented. Two approaches have been developed to construct the basic pyrrolo[1,2-a]azepine core of the Stemona alkaloids, featuring a tandem semipinacol/Schmidt rearrangement of a secondary azide and a highly stereoselectively desymmetrizing intramolecular Schmidt reaction, respectively. To build the common spiro-γ-butyrolactone, a new protocol was carried out by utilizing an intramolecular ketone-ester condensation as the key transformation. The vicinal butyrolactone moiety of (±)-maistemonine was stereoselectively introduced via a one-pot procedure involving the epimerization at C-3 and carbonyl allylation/lactonization. Moreover, (±)-stemonamide was divergently synthesized from a common intermediate, and (±)-isomaistemonine was obtained via the epimerization of (±)-maistemonine at C-12." @default.
- W2072265937 created "2016-06-24" @default.
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- W2072265937 date "2011-11-23" @default.
- W2072265937 modified "2023-09-26" @default.
- W2072265937 title "Total Synthesis of (±)-Maistemonine, (±)-Stemonamide, and (±)-Isomaistemonine" @default.
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- W2072265937 cites W1983371652 @default.
- W2072265937 cites W1983725821 @default.
- W2072265937 cites W1995239569 @default.
- W2072265937 cites W2005989425 @default.
- W2072265937 cites W2009491154 @default.
- W2072265937 cites W2012506141 @default.
- W2072265937 cites W2014613303 @default.
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- W2072265937 cites W2043077062 @default.
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- W2072265937 doi "https://doi.org/10.1021/jo202042x" @default.
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