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- W2072284611 abstract "Ice IV was prepared in a reproducible manner on heating high-density amorphous ice (HDA) at pressure of 0.81 GPa up to ≈162 K at a slow rate of ≈0.5 K min-1, quenching thereafter to 77 K, and recovering the sample under liquid N2 at 1 bar. Recovered ice IV was characterized by X-ray diffraction and it was free of HDA or of low-density amorphous ice. D2O ice IV contained no crystalline impurities, whereas the H2O sample contained a minor impurity of ice XII. D2O ice IV with 11 mol % HOD and H2O ice IV with 9.0 mol % HOD were studied in vacuo by Raman spectroscopy between 80 and 145 K. The decoupled O−D (O−H) stretching band in H2O (D2O) ice IV consists of two overlapping peaks centered at 2500 (3390) and 2458 (3322) cm-1 at 80 K. Peak maximum of the coupled O−H (O−D) stretching band region is at 3200 (2360) cm-1. At low frequency a band at ≈498 (≈365) cm-1 is assigned to a librational mode, whereas bands at ≈252 (≈250), 208 (203), 178 (172), 152 (149) and 126 (123) cm-1 originate from translation modes. On heating ice IV, we measured the development of peak-positions and the phase transition from ice IV to ice I. We did not observe indication for formation of an amorphous phase during this transition. Curve resolution of the decoupled O−D stretching transition region into two component bands is consistent with the assignment of the high-frequency band centered at 2500 cm-1 to the O−D···O H-bonds with 2.88 and 2.92 Å length, and of the low-frequency component band centered at 2458 cm-1 to H-bonds with 2.79 and 2.81 Å length. The composite band shape is consistent with large fwhh's (full width at half-heights) of the distinct bands from the four types of H-bonds." @default.
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- W2072284611 date "2003-02-28" @default.
- W2072284611 modified "2023-09-27" @default.
- W2072284611 title "Raman Spectroscopic Study on Hydrogen Bonding in Recovered Ice IV" @default.
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- W2072284611 doi "https://doi.org/10.1021/jp021534k" @default.
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