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• W2072288163 abstract "Electron paramagnetic resonance (EPR) has been used to characterize a new hole trap in flux-grown KTiOPO4 crystals. This center is formed at room temperature when the crystals are exposed to either 60 kV x rays or a pulsed 355 nm laser beam. Principal g values measured at room temperature are 2.0030, 2.0102, and 2.0320. The intensity of the EPR spectrum is considerably larger in a silicon-doped sample, thus suggesting that the responsible defect consists of a hole trapped on an oxygen ion adjacent to a silicon impurity located on a phosphorus site. Also, a broad optical absorption band peaking near 500 nm has been observed in the irradiated samples. The silicon-associated hole centers thermally decay over a period of several days at room temperature as electrons are released from Ti3+ traps. Analysis of hole-center decay curves obtained at three temperatures (291, 300, and 311 K) has shown that the kinetics of this electron-release process are primarily second order. The activation energy is approximately..." @default.
• W2072288163 created "2016-06-24" @default.
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• W2072288163 date "1999-01-15" @default.
• W2072288163 modified "2023-09-27" @default.
• W2072288163 title "Role of silicon impurities in the trapping of holes in KTiOPO4 crystals" @default.
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• W2072288163 doi "https://doi.org/10.1063/1.369229" @default.
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