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- W2072332806 abstract "The behaviour of stress relaxation after steady-state shear flow of polydisperse polymers was calculated starting from the experimental evidence that stress relaxation of a monodisperse polymer can be expressed by an Erfc function against log t. The results of this analysis are: (a) stress relaxation curves for polydisperse polymers are Erfc functions, i.e. the experimental data plotted on log-probability paper lie on a straight line; (b) the slope of this straight line depends on the heterogeneity and probably also the position depends only on heterogeneity. These facts were experimentally confirmed and the following experimental conclusions were obtained: the mixing rule for the fractions is not linear; the relaxation time is not proportional to ηM, its proportionality to η seems to be preferable than that to ηM; both the slope and position of the relaxation curve, when plotted on log-probability paper, are linked with the heterogeneity ratio M̄w-Mn in such a way that its determination from stress relaxation measurements is possible." @default.
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- W2072332806 date "1972-08-01" @default.
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- W2072332806 title "Stress relaxation after steady-state shear flow in undilute polydisperse polymers" @default.
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- W2072332806 doi "https://doi.org/10.1016/0032-3861(72)90061-4" @default.
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