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- W2072345549 abstract "Allylic organotin compounds react with numerous organic halides by a substitution pathway with complete allylic shift. The radical chain mechanism proposed is supported by the reactivity sequences of halides, the stereochemistry, the influence of radical initiators or inhibitors, rearrangement, polar effects and the side products. Les dérivés organostanniques allyliques réagissent avec divers halogénures organiques en donnant lieu à une substitution accompagnée de transposition allylique totale. Un mécanisme radicalaire en chaîne rend compte de l'ensemble des résultats expérimentaux: séquences de réactivité de différents types d'halogénures, stéréochimie, influence d'initiateurs et d'inhibiteurs radicalaires, transpositions, effets polaires et présence de produits secondaires." @default.
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- W2072345549 date "1975-08-01" @default.
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- W2072345549 title "Reactivite des organostanniques allyliques vis-a-vis des derives halogenes: aspects synthetiques et mecanisme" @default.
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- W2072345549 doi "https://doi.org/10.1016/s0022-328x(00)83550-0" @default.
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