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- W2072360189 abstract "The reduction reactions of trans- and/or cis-[PtCl4(NRH2)2] by [Fe(η5-C5H5)2], Nal, and [Pt(NEtH2)4][ClO4]2 in the presence of chloride ions have been kinetically investigated in methanol [R = H, Me, Et, Prn, Pri, Bun, Bui, Bus, But, CH2But, CH2Ph, or cyclo-C6H11]. The rate constants for the cis complexes are sensitive to both σ-donor ability and steric hindrance of R, according to relationships of the Taft's type: log kred=a+ρI[–σI(R)]+ρS[–ES(R)]. The rates are increased by lowering the σ-donor ability of R and by increasing its bulkiness; the trans complexes behave similarly." @default.
- W2072360189 created "2016-06-24" @default.
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- W2072360189 date "1984-01-01" @default.
- W2072360189 modified "2023-10-16" @default.
- W2072360189 title "An investigation on the influence of co-ordinated aliphatic amines on the rates of reduction of tetrachlorodiamineplatinum(IV) complexes" @default.
- W2072360189 doi "https://doi.org/10.1039/dt9840000249" @default.
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