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- W2072435970 abstract "The measured fluorescence spectra of biphenyl (BP) and para-terphenyl (PTP) in solution reveal with decreasing temperature first an increasing structure and a slight red shift and below the glass transition a loss in structure and a strong blue shift. The effect is discussed using a torsional potential scheme in agreement with QCFF/PI calculations. Comparison of the experimental blue shifts with the results of CNDOS calculations suggest an incomplete hindrance of the relaxation process of the unsubstituted molecules. A nearly perfect hindrance could be detected for the tetra-methyl substituted BP and PTP molecules." @default.
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- W2072435970 date "1987-06-01" @default.
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- W2072435970 title "Hindrance of the rotational relaxation in the excited singlet state of biphenyl and para-terphenyl in cooled solutions by methyl substituents" @default.
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- W2072435970 doi "https://doi.org/10.1016/0022-2313(87)90192-x" @default.
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