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• W2072443432 endingPage "4655" @default.
• W2072443432 startingPage "4651" @default.
• W2072443432 abstract "A powder electron-paramagnetic-resonance study of ${mathrm{Cu}}^{2+}$ in ${mathrm{ZnTiF}}_{6}$ensuremath{cdot}${6mathrm{H}}_{2}$O has been made at 35 GHz in the range 4.2--300 K. The low-temperature structure has been related to four single-crystal Jahn-Teller transitions. The single-line spectrum at high temperature was replaced gradually by a multiline spectrum at temperatures below 165 K, i.e., about 6 K below the single-crystal transition temperature for 0.043 at. % ${mathrm{Cu}}^{2+}$ concentration. The exponential line broadening with temperature in the high-temperature region (above phase transition) was fitted to an Orbach process, with an excited state at 1350 ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$. A Jahn-Teller stabilization energy ${E}_{mathrm{JT}=1000}$ ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ may be obtained from this fit. The relaxation rate 1/${T}_{1}$ is deduced and compared with that for ${mathrm{Cu}}^{2+}$:${mathrm{La}}_{3}$${mathrm{Mg}}_{2}$(${mathrm{NO}}_{3}$) $_{12}mathrm{O}$." @default.
• W2072443432 created "2016-06-24" @default.
• W2072443432 creator A5069655980 @default.
• W2072443432 date "1986-10-01" @default.
• W2072443432 modified "2023-09-24" @default.
• W2072443432 title "Powder EPR study of the Jahn-Teller effect and phase transition in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=normal>Cu</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>:<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>ZnTiF</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn…" @default.
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• W2072443432 doi "https://doi.org/10.1103/physrevb.34.4651" @default.
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