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- W2072446066 abstract "A simple method to evaluate fluorescence quantum yields using front surface geometry and based on corrected fluorescence emission spectra of dyes on diluted and strongly absorbing solutions was developed. The method is supported by a detailed knowledge of the apparatus geometry and energy profile of excitation, and uses an experimentally determined correction factor f. This factor relates the intensity of fluorescence obtained in the general case with the maximum value for the emission intensity obtained for very high optical densities. The method was applied to rhodamine 700 (R700) in ethanol and bis[4-(dimethylamino)-2-methylphenyllsquaraine (MeSQ) in dichloromethane in concentrations ranging from ∼ 10−6 to ∼ 10−3 M in both cases. The data shows a substantial quenching effect in the former case for very concentrated samples of the dye whereas no such effect was found in the methylsquaraine within experimental error." @default.
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- W2072446066 date "1991-01-01" @default.
- W2072446066 modified "2023-09-25" @default.
- W2072446066 title "Fluorescence quantum yield evaluation of strongly absorbing dye solutions as a function of the dye concentration" @default.
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- W2072446066 doi "https://doi.org/10.1016/0022-2313(91)90146-m" @default.
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