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- W2072457433 abstract "Recent achievements in two catalytic reactions, i.e., silylative coupling and cross-metathesis of alkenes and dienes with vinyl-silicon compounds, which resulted in new synthetic routes to organosilicon molecular and macromolecular compounds are presented. The silylative coupling, also called dehydrogenative or trans-silylation and silyl group transfer, is catalyzed by metal complexes which either contain or initiate the formation of M-H and M-Si bonds, where M = Ru, Rh, Co and fr. Cross-metathesis, which was developed very recently, proceeds in the presence of metallacarbenes, mainly those of ruthenium (e.g., Grubbs catalyst)." @default.
- W2072457433 created "2016-06-24" @default.
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- W2072457433 date "2003-09-26" @default.
- W2072457433 modified "2023-10-17" @default.
- W2072457433 title "Silylative Coupling and Cross-Metathesis of Alkenes and Dienes with Vinyl–Silicon Derivatives— New Catalytic Routes to Synthesis of Organosilicon Compounds" @default.
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- W2072457433 doi "https://doi.org/10.1002/9783527619924.ch63" @default.
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