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- W2072470033 abstract "The diiron μ-vinyl complex [Fe2Cp2(CO)2(μ-CO){μ-η1:η2-CH═CH(Ph)}][BF4], [1][BF4], reacted with CoCp2 affording selectively the C–C coupling product [Fe2Cp2(CO)2(μ-CO){μ-CHCH(Ph)}]2, 2. The cation [1]+ was regenerated from 2 in good yield by I2-induced oxidative cleavage. The cation [1]+ underwent two sequential monoelectron reductions, the first one being an electrochemically reversible process that generated the radical species [Fe2Cp2(CO)2(μ-CO){μ-CHCH(Ph)}], [1]•. The latter was characterized by EPR spectroelectrochemistry. The structures of [1]+, [1]•, and 2 were optimized for the gas phase by DFT calculations. The reaction of [1][BF4] with NEt3 in the presence of excess PhSSPh gave [Fe2Cp2(CO)2(μ-CO){μ-CHCH(Ph)(SPh)}], 3. The new compounds 2 and 3 were fully characterized by IR and NMR spectroscopy, elemental analysis, and X-ray diffraction studies." @default.
- W2072470033 created "2016-06-24" @default.
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- W2072470033 date "2011-07-06" @default.
- W2072470033 modified "2023-09-30" @default.
- W2072470033 title "Reversible Reductive Dimerization of Diiron μ-Vinyl Complex via C–C Coupling: Characterization and Reactivity of the Intermediate Radical Species" @default.
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- W2072470033 doi "https://doi.org/10.1021/om200421a" @default.
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