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- W2072479186 abstract "Abstract Part of molybdenum introduced in SnO 2 by various methods is found to be stabilized in the pentavalent state at substitutional positions. The ESR spectra of Mo 5+ ions are characterized by the following parameters: g xx = 1.891; g yy = 1.835 and g zz = 1.923, A xx = 24 G, A yy = 30 G and A zz = 70 G. There are, in addition, two sets of superhyperfine structures due to the two tins located along the crystallographic c axis (290 G) and to the four tins lying in a diagonal plane of the unit cell containing four oxygens (51 G), consistent with a 3d x 2 - y 2 + λ 3d z 2 ground state. The variations of the Mo 5+ ESR spectrum upon heating the samples in various atmospheres (O 2 , H 2 ) suggest that molybdenum enters the SnO 2 lattice also as Mo 4+ ." @default.
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- W2072479186 date "1975-03-01" @default.
- W2072479186 modified "2023-09-26" @default.
- W2072479186 title "Paramagnetic absorption of pentavalent molybdenum in polycrystalline tin dioxide" @default.
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- W2072479186 doi "https://doi.org/10.1016/0009-2614(75)85082-2" @default.
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