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- W2072485323 abstract "Our previous determination of the structures of 2-methyl- and 3-methyl-cymantrene sulfonic acids by NMR and chromatographic methods is now confirmed by an unambigous chemical method. The influence of the methylthio group on the electrophilic substitution of 2-methyl- and 3-methyl-methylthiocymantrene is studied by acylation. Each sulphur gives three ketonic isomers whose structures and relative yields are discussed with reference to the NMR spectra. La configuration vraisemblable des isoméres obtenus par sulfonation du méthylcymantrène ayant été établie précédemment sur la base des données de RMN, il appartenait de la confirmer par vole chimique univoque. L'étude de l'influence du groupement sulfure dans l'orientation d'une substitution électrophile sur le cycle a été étudiée. L'acylation des méthyl-2 et méthyl-3 méthylthio cymantrène conduit à 6 cétones isomères dont la structure et les pourcentages relatifs ont été déterminés par RMN." @default.
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- W2072485323 date "1977-10-01" @default.
- W2072485323 modified "2023-10-14" @default.
- W2072485323 title "Derives soufres du methylcymantrene" @default.
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- W2072485323 doi "https://doi.org/10.1016/s0022-328x(00)91244-0" @default.
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