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• W2072500778 abstract "Rhodium(III)porphyrins catalyze the decomposition of ethyl diazoacetate and the transfer of ethoxy-carbonylcarbene to alkenes to form cyclopropanes in moderate to high yields. When compared with other catalysts a large syn-selectivity was observed on reaction with cis-alkenes. This selectivity increased with the size of the substituents, and suggested a preferential direction of approach of the alkene towards a rhodium—carbene complex." @default.
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• W2072500778 date "1982-01-01" @default.
• W2072500778 modified "2023-10-16" @default.
• W2072500778 title "Sterically crowded cyclopropanation catalysts. Syn-selectivity using rhodium(III)porphyrins" @default.
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• W2072500778 doi "https://doi.org/10.1016/0040-4020(82)87014-2" @default.
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