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- W2072534850 abstract "The second-order rate constants of the reactions between benzenesulphonyl chlorides and anionic nucleophiles, benzoates and cinnamates, in methanol at 30·0°C are reported. A marked increase in rate found with a p-nitro substituent in the substrate indicated the development of an electron-rich centre on the S atom in the transition state. The two types of cross-interaction constants, ρxy and λxy, suggested that bond formation in the SN2 transition state with anionic nucleophiles is greater than that for the corresponding reaction with aniline nucleophiles." @default.
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- W2072534850 date "1990-08-01" @default.
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- W2072534850 title "Cross-interaction constants as a measure of the transition state structure. Part 9. The degree of bond formation in theSN2 transition state involving anionic nucleophiles" @default.
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- W2072534850 doi "https://doi.org/10.1002/poc.610030809" @default.
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