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- W2072536917 abstract "ABSTRACT To evaluate the existence of the depropagation reaction in the copolymerization of vinyl monomers, the cationic copolymerization of α-methylstyrene with styrene was studied. The copolymer composition exhibited an extensive dependency on the temperature of polymerization and the monomer concentration, this fact not being explained by the Mayo-Lewis equation. Treatment of the copolymerization in terms of the depropagation reaction led to an estimate of the monomer reactivity ratio and the equilibrium constant between the polymer and the monomer of α-methylstyrene. A comparison of the equilibrium constants thus obtained with those reported in the literature indicates that the magnitude of the equilibrium constants depends on the sequence length of α-methylstyrene units. By extrapolation to long sequence length, the equilibrium constants approach the values which are reported for high molecular weight poly(α-methylstyrene)." @default.
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- W2072536917 date "1972-01-01" @default.
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- W2072536917 title "Cationic Copolymerization with Depropagation. The Copolymerization of α-Methylstyrene and Styrene" @default.
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- W2072536917 doi "https://doi.org/10.1080/0022233x.1972.10131858" @default.
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