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- W2072553522 abstract "The gas phase elimination kinetics of the title compound was studied over the temperature range of 260.1–315.0°C and pressure range of 20–70 Torr. This elimination, in seasoned static reaction system and in the presence of at least fourfold of the free radical inhibitor toluene, is homogeneous, unimolecular and follows a first-order rate law. The reaction yielded mainly benzaldehyde, CO, and HBr, and small amounts of benzylbromide and CO2. The observed rate coefficients are expressed by the following Arrhenius equations: For benzaldehyde formation: log k1 (s−1) = (12.23 ± 0.26) − (164.9 ± 2.7) kJ mol−1 (2.303 RT)−1 For benzylbromide formation: log k1 (s−1) = (13.82 ± 0.50) − (192.8 ± 5.5) kJ mol−1 (2.303 RT)−1 The mechanisms are believed to proceed through a semi-polar five-membered cyclic transition state for the benzaldehyde formation, while a four-centered cyclic transition state for benzylbromide formation. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 725–728, 1999" @default.
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- W2072553522 date "1999-01-01" @default.
- W2072553522 modified "2023-09-25" @default.
- W2072553522 title "Kinetics of the gas-phase elimination of ?-Bromophenylacetic acid under maximum inhibition" @default.
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- W2072553522 doi "https://doi.org/10.1002/(sici)1097-4601(1999)31:10<725::aid-jck5>3.0.co;2-v" @default.
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