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- W2072592511 abstract "A mixed oxidation-state (Rh24+ and Rh25+) complex, [{Rh2(acam)4}2(μ4-ReO4)] (1, Hacam = acetamide), was synthesized and characterized by X-ray structure analysis. A square-sheet structure is constructed from Rh2(acam)4 units and ReO4− ion linkers in which all dirhodium units are crystallographically equivalent. In the mixed oxidation-state compounds, the electrical conductivity of 1 (8.9 × 10−6 S cm−1) is higher than that of [{Rh2(acam)4}3(μ3-Cl)2]·4H2O, but lower than that of [{Rh2(acam)4}2(μ4-I)]·6H2O." @default.
- W2072592511 created "2016-06-24" @default.
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- W2072592511 date "2006-11-01" @default.
- W2072592511 modified "2023-09-26" @default.
- W2072592511 title "A Square-sheet Structure of Paddlewheel Dirhodium Complexes in Mixed Oxidation States with Perrhenate Linkers" @default.
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- W2072592511 doi "https://doi.org/10.1246/cl.2006.1298" @default.
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