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• W2072644260 abstract "Abstract The copper complexes [Cu(4‐MeBPI)(OAc)] ( 4 ), [Cu(4‐Me‐10‐ t BuBPI)(OAc)] ( 5 ) and [Cu(BTI)(OAc)] ( 6 ) [BPI = 1,3‐bis(2‐pyridylimino)isoindole, BTI = 1,3‐bis(2‐thiazolylimino)isoindole] were prepared by reaction of the protio ligands with copper( II ) acetate. Compounds 4 and 6 were characterized by X‐ray diffraction, establishing distorted square‐planar coordination geometries of the copper ions. Two monoclinic modifications of 6 ( 6a and 6b ) were found, both crystallizing in the space group P 2 1 / c , but possessing different cell parameters. In contrast to 6a , which is monomeric in the crystal, the second monoclinic modification 6b has a more complicated crystal structure, which is composed of both monomeric complex units such as those found in 6a and infinite chains of coordination polymers. The copper atoms in the polymeric chains of 6b display fivefold coordination and a ligand polyhedron that is an intermediate form between a trigonal‐bipyramidal and a square‐pyramidal geometry. The allylic peroxylation of cyclohexene with t BuOOH (70% aqueous solution) catalyzed by 4 and 6 (0.17 mol %) gave tert ‐butylperoxy‐3‐cyclohexene with selectivities of 86% and 80% (based on cyclohexene) and turnover frequencies of 63 h −1 and 18 h −1 , respectively. The peroxylation reaction is thought to proceed according to a Haber−Weiss radical chain mechanism. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
• W2072644260 created "2016-06-24" @default.
• W2072644260 creator A5049840515 @default.
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• W2072644260 date "2004-06-22" @default.
• W2072644260 modified "2023-10-18" @default.
• W2072644260 title "Coordination Chemistry of 1,3‐Bis(2‐pyridylimino)‐ and 1,3‐Bis(2‐thiazolylimino)soindole Copper Complexes: Investigation of Their Catalytic Behavior in Oxidation Reactions" @default.
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• W2072644260 doi "https://doi.org/10.1002/ejic.200400012" @default.
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