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• W2072647892 abstract "Fourier transform spectra of collisionally induced fluorescence following isotopically selective laser excitation of NiH at ∼550 nm have located an excited Ω = 1/2 state of NiH lying 17900 cm−1 above the electronic ground state. This is identified as v = 0 of a 2Π1/2 state originating from an Ni+ 3d84s1 2F configuration. Emission from this Ω′ = 1/2 state occurs predominantly to v″ = 0 and 1 of the 2Σ+ and W2 2Π1/2 ligand field states, locating elusive f parity levels of W2 2Π1/2 up to 5600 cm−1 above the first rotational level of the electronic ground state, X 1 2Δ5/2. Collisionally induced fluorescence following laser excitation at lower energies has also been recorded in the presence of a magnetic field (0.7–1 T), at Doppler limited resolution. Effective Landé factors g J for rotational levels of the v = 0 and 1 levels of the low-lying Ω″ = 5/2 and 3/2 components of the 2Δ and 2Π states of NiH have been derived from partially resolved Zeeman patterns. About 1600 transitions recorded in field-free conditions have been reduced to term energies relative to the lowest level of the ground state. They confirm strong spin-orbit mixing between the low-lying ligand-field states." @default.
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• W2072647892 date "2012-09-01" @default.
• W2072647892 modified "2023-10-14" @default.
• W2072647892 title "Resolved fluorescence spectra of NiH. Electronic structure, electronic energy transfer, and the Zeeman effect in low-lying states" @default.
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• W2072647892 doi "https://doi.org/10.1080/00268976.2012.655336" @default.
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