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- W2072670004 abstract "The electrochemical oxidation of tyrosine has been studied on polycrystalline and (1 1 1) single crystal platinum electrodes in 0.1 M HClO4. No surface sensitivity of bulk tyrosine reactions has been detected for these two electrodes, although the adsorption process seems to be structure-sensitive. The onset for tyrosine electrooxidation is observed at ca. 0.7 V for both surfaces. In situ FTIR technique was used to discern the nature of the products formed during the oxidation processes. The early stages of tyrosine oxidation occur via a decarboxylation to carbon dioxide. Two complex parallel reactions were found at E > 1.10 V vs. RHE: one of them leading to a ?-lactone of hydroxy-substituted benzofurane, and the second with the formation of p-benzoquinone. The assignment of these products is based on the corresponding transmission spectra." @default.
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- W2072670004 date "2005-11-01" @default.
- W2072670004 modified "2023-10-16" @default.
- W2072670004 title "FTIR studies of tyrosine oxidation at polycrystalline Pt and Pt(111) electrodes" @default.
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- W2072670004 doi "https://doi.org/10.1016/j.jelechem.2005.08.014" @default.
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