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- W2072670699 abstract "The metallation (n-BuLi), alkylation (t-BuOH/H+), nitration (NO2+ BF4−), bromination (NBS, dioxane dibromide (DDB)), acylation [(CF3CO)2O] and chlorination (chloramine T) reactions of (2-furyl)germanes were studied. Except for alkylation and bromination with DDB, the reactions involved electrophilic substitution of hydrogen atoms in position 5 or 3 of the furan ring. The alkylation reaction and bromination with DDB occur via ipso-substitution of the trialkylgermyl group. Dichlorocarbene generated by phase-transfer catalysis adds to the 2-germyl-substituted furan at the C4C5 bond in the ring. Some of the above reactions were conducted with trimethyl(2-furyl)silane and 2-(t-butyl)furan, the silicon and carbon analogues of furylgermanes. The reactivities of the title compounds were compared." @default.
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- W2072670699 date "1988-06-01" @default.
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- W2072670699 title "Reactions of trialkyl(2-furyl) germanes with electrophilic reagents" @default.
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- W2072670699 doi "https://doi.org/10.1016/0022-328x(88)80334-6" @default.
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